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1 article(s) from Roy, Olivier

First series of N-alkylamino peptoid homooligomers: solution phase synthesis and conformational investigation

Maxime Pypec,
Laurent Jouffret,
Claude Taillefumier and
Olivier Roy

Beilstein J. Org. Chem. 2022, 18, 845–854, doi:10.3762/bjoc.18.85

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Graphical Abstract

Figure 1: (A) Summary of the main side chains exerting significant steric and/or electronic effects and influ...

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Figure 2: Solution-phase synthesis of N-(methylamino)glycine oligomers using N-Boc-N-methylhydrazine as a sub...

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Scheme 1: Submonomer synthesis used for the construction of peptoids 1–5 containing N-methylamino side chains...

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Scheme 2: Evaluation of the efficiency of mixed anhydride methods by coupling of 1a and 1c.

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Scheme 3: (3 + 3) segment coupling of trimers 3-OH onto trimer hydrazine 3a.

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Figure 3: X-ray crystal structure of peptoid dimer 2: (A) single molecule; (B) unit cell, view along b axis (...

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Figure 4: NOE effect interaction observed in the 2D-NOESY spectra of monomer 1 and dimer 2 in DMSO-d₆.

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Figure 5: Comparison of monomers A and B with respect to their ability to form intramolecular and intermolecu...

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Figure 6: Model structure of N-(NMe)glycine peptoid. (A) dimer in the repeating (pp) conformation; (B) dimer ...

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Published 14 Jul 2022

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